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Chemical Storage Units

Oscillating chemical reactions occur far beyond thermodynamic equilibrium. The Belousov -Zhabotinsky (BZ) reactions are among the most thoroughly investigated of these. In the BZ reaction a dicarboxylic acid, for example, is oxidized by bromate in acidic solution. A redox-active species, whose oxidized and reduced forms differ in color, acts as the catalyst. Its periodic concentration fluctuations can be followed by the oscillating color change of the reaction mixture.